The Switch on the Bussman Circuit breakers is likely not rated for 100's of cycles. Their contacts inside will wear out, become more resistive, and then it will start tripping at much lesser amperages than their ratings.
If one wanted a manual switch, to manually bring the house battery into the alternator charging circuit, this is the product you want:
https://www.bluesea.com/products/6006/m-Series_Mini_On-Off_Battery_Switch_with__Knob_-_Red
There are so many methods and products to allow battery charging of house batteries protecting engine battery from house loads that it is an entire thread on its own.
The Bussman CB shown in the OP does not show the push button disconnect nor the lever reconnect, and I cannot even find such a product in their catalog, so I believe it is quite old. To pass ABYC codes the terminals where the cables connect have to be covered with the rubber boots. AFAIK, there is no switch under the rubber boots.
One could certainly retask the cabling which runs back to the wheelchair lift. My buddy's used sprinter van used 4awg for the lift, and a frame ground, but I found green corrosion wicking up under the insulation a foot from its end, and do not want to retask it for battery charging. I also found some wire chafing and cracked insulation under the body.
Also the length and the TPPL AGM battery bank would be so much better off with thicker cabling which would pass much higher amperages to these 'thirsty' distant batteries. He's old and loves to argue so the project sits until he does it himself, or acknowledges that he is not right, and that green corroding 4awg copper and cracked insulation wrapped with electrical tape or self fusing silicone tape, is not 'just fine' because he can't envision how it cannot pass enough current to make 800$ of depleted AGM battery happy.
Also I would much prefer to take power from Alternator (+) stud than from engine battery (+) stud, as the original OEM circuit was never designed to pass the extra current to depleted batteries, especially TPPL AGM's( thin plate pure lead), and becomes a bottle neck which limits charging amps because of longer circuit length, increased resistance, and resultant voltage drop. I have issues when asked to use only half my ass on projects, and usually turn them down.
So often attempt to save money come back and shoot one in the foot and then smear feces into the wound, especially regarding electricity.