A full on hair dryer on high heat is 1800 watts. A small space heater is 1000 watts. A small space heater on low heat will be about 500 watts. A Mr Heater Little buddy is 3800 BTU per hour. That is waaaaay too much heat for a mini-van or hatchback. 500 watts is 1700 BTU per hour and still likely too much for a hatchback unless it is really cold but probably good if it is 0 F, -18 C. Above freezing 200 or so watts will keep away the chill.
To have batteries provide 200 watts for 10 hours means 2000 watt hours. During the remaining 14 hours in the day you need other arrangements. Recharging the 2000 watt hours will take 2400 watt hours, there is loss. The Battleborn 100 amp hours times 12 volts should be 1200 watt hours. Since you can't run them down to zero and recharging to 100% full is a challenge, figure 1000 watt hours each rather than 1200 to avoid disappointment. A big battery bank cannot be recharged by idling the engine of the Kia for a few minutes or even a few hours.
A quick estimate: two batteries, 1 kilowatt, 1 kilo buck, would be a starting point. Solar panels to charge that will require more space than a Kia Rio roof. Actually, it will probably more space than an entire Kia Rio considering the poor charging conditions of winter.
A mobile electric supply for electric heat will be expensive. If you can arrange a place to plug in an extension cord the power requirement is not very high but the daily energy requirement is large due to the many hours of on time.