To whomever it may concern:
IMHO, to safely charge an AGM battery (or even two!) which are lead acid and follow typical lead acid charge profiles, you need an adequately sized automotive stranded copper wire, grounded back to the block (not the van body), fuzing to protect said wire rating and finally, proper crimping.
Now whether an older alternator will ever get two 100 amp deep cell AGM's fully charged is, well, rather optimistic thinking.
If the OP checks published AWG wiring charts he can ascertain the recommended wire sizes. To undersize will produce resistance/slow charging/heat and to significantly oversize merely wastes $$.
It should be noted that many Chrysler/Dodge vans had 10 gauge fusible links in their alternator to battery wiring from the factory so a 2 or even a 4 gauge (horrors) AWG stranded copper wire should suffice for what he is hoping/intending to do.
If the OP so chooses, he could do a search under the heading "big 3 wiring upgrade" and see what the audiophiles do to upgrade their stock vehicle electrical systems. A link for such an article is here:
https://www.crutchfield.com/S-KJqGgZPwKVP/learn/big-3-alternator.html
A quotation from that same article says:
The Big Three wiring upgrade
"A good, cost-effective improvement is to perform the "Big Three" electrical upgrade. This will vastly improve your vehicle's electrical system, allowing more current to flow easier to all components. This upgrade replaces or augments three key cables in the electrical system with 1/0 or 4 gauge wires: the battery ground to chassis wire, the chassis to engine block wire, and the alternator plus to battery plus wire. This increases your electrical system's current flow capability, ensuring a more consistent voltage under varying demand conditions.
An unfortunate possible side effect of doing the Big Three is that occasionally it only makes your lights dim even worse. This happens because the amplifier is now able to suck juice better from the system through the bigger straw (the new cables). " (End of copied portion)
The OP admits that automotive electricals is not his strong suit, (the same with most people). A little research on the web will show him factual, proven information as opposed to forum chatter.
Thanks to ALL of you who are attempting to steer him in the right direction. Like in all things, there is a spectrum of possible ways to do it from cheap to costly. I am merely advocating "good enough", the same on the towing with a car thread... (Oops, may have done some "she-it disturbing" with that one...)