I think all the insulations that are used in air, use air for insulation. Certainly wool and rock-wool, cellulose, fiberlgass, foams, etc. Except for the radiation foils that don't work very well except in space. The insulations I designed for space were many-layered sheets of mylar plated with gold (or sometimes aluminum), separated by light nylon scrim.
I wouldn't look to NASA for the best thing to use in a van... they have very different requirements and budgets. In a small space, air exchange is a big heat load, thermal bridging, windows, etc.
The wool absorbs moisture, but if you aren't giving it chance to then dry out, I doubt you will have a good result.
If you seal it very well, the pink XPS foam sheets they sell at HD would probably work well, as they don't transmit or absorb moisture. Glue them on and seal any gaps.
Water condenses wherever there is a surface below the dew point. An insulation that passes air will have water condensing on the inside of the outer wall.