First off, the tank says right on it "TW" followed by a number, which is the tare weight or empty weight. You should use that number for your calculations as not every 40lb tank weighs the same empty. The "WC" stamp is the water capacity. I have a tank that reads WC in gallons, but it can also be in pounds, and either way can give you the volume, of which you can use 80%.
Caution for the next part: Liquid propane will instantly freeze your skin or with whatever it comes in contact. Be careful!
There is a valve gauge for 80% filled. If the propane technician doesn't use it, learn to use it yourself. The gauge, which is really a valve, can be the type you can turn with your finger or use a small flat head screwdriver to loosen until you hear the hissing vapor, then gently rock the tank, and if it's full, it should spit liquid propane intermittently with vapor. If it's all vapor, then the tank is not full. If it's all liquid, the tank is overfilled.